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https://www.ganoksin.com/article/pickling-notes/
Here is what I think happened: jewelers used alum and salts to pickle with, then in the 19th century mineral acids became cheaper and more available, which along with the rise in industrialization and the increasing need for speed caused sulfuric acid to become the standard pickling solution. Sulfuric acid however is dangerous to store, handle and mix up.
https://juxtamorph.com/pickle-solution-for-cleaning-jewelry/
When there is a sulfuric acid component in these solutions it is already diluted with water to a standard pickle consistency of 5-10%. If you are starting with concentrated acid, remember: always add the acid to the water, not the other way around, and wear nitrile gloves and chemical-splash rated goggles.
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